How does strength of boric acid solution increase in presence of salicylic acid?
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 2 days ago
andselisk
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asked 2 days ago
RicheekRicheek
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 2 days ago
andselisk
19k660125
asked 2 days ago
RicheekRicheek
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
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see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago
add a comment |
$begingroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 2 days ago
andselisk
19k660125
asked 2 days ago
RicheekRicheek
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
inorganic-chemistry acid-base
edited 2 days ago
andselisk
19k660125
asked 2 days ago
RicheekRicheek
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
edited 2 days ago
andselisk
19k660125
asked 2 days ago
RicheekRicheek
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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edited 2 days ago
andselisk
19k660125
edited 2 days ago
andselisk
19k660125
edited 2 days ago
andselisk
19k660125
19k660125
asked 2 days ago
RicheekRicheek
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
asked 2 days ago
RicheekRicheek
534
asked 2 days ago
RicheekRicheek
534
534
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago
add a comment |
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago
add a comment |
2 Answers
2
active
oldest
votes
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Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited yesterday
Gaurang Tandon
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 2 days ago
PoutnikPoutnik
77728
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add a comment |
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2 Answers
2
active
oldest
votes
2 Answers
2
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited yesterday
Gaurang Tandon
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited yesterday
Gaurang Tandon
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited yesterday
Gaurang Tandon
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
$endgroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited yesterday
Gaurang Tandon
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
edited yesterday
Gaurang Tandon
5,32862764
edited yesterday
Gaurang Tandon
5,32862764
edited yesterday
Gaurang Tandon
5,32862764
5,32862764
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
answered 2 days ago
William R. EbenezerWilliam R. Ebenezer
75914
75914
add a comment |
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 2 days ago
PoutnikPoutnik
77728
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 2 days ago
PoutnikPoutnik
77728
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 2 days ago
PoutnikPoutnik
77728
$endgroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 2 days ago
PoutnikPoutnik
77728
answered 2 days ago
PoutnikPoutnik
77728
answered 2 days ago
PoutnikPoutnik
77728
answered 2 days ago
PoutnikPoutnik
77728
77728
add a comment |
add a comment |
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$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
2 days ago